Reinholdt, Anders; Alemayehu, Abraham; Gagnon, Kevin J.; Bendix, Jesper; Ghosh, Abhik (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-03-31)
Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouched. The OsN unit is also unaffected by a variety of other electrophilic and nucleophilic reagents. Upon photolysis, ...